There were 15 goals in 4 La Liga matches on Saturday 31 October.
- Levante 0–2 Atlético Madrid. Atlético Madrid: Alejandro Grimaldo (36′) and Giuliano Simeone (62′).
- Rayo Vallecano 3–0 Celta Vigo. Rayo Vallecano: Jorge de Frutos (36′, 55′) and Unai López (73′).
- Real Betis 2–1 Málaga. Real Betis: Marc Bartra (38′) and Pablo Fornals (45+2′). Málaga: Adrián Niño (68′).
- FC Barcelona 6–1 Deportivo Alavés. FC Barcelona: Raphinha (8′, 41′), Fermín López (23′), Lamine Yamal (45+1′, 64′) and Anthony Gordon (81′). Deportivo Alavés: Mariano Díaz (84′).
FC Barcelona’s 6–1 against Deportivo Alavés was the day’s biggest win. The most goals came in FC Barcelona 6–1 Deportivo Alavés, 7 in all.